Photodissociation of cyanide
WebPhotodissociation is a method to activate molecules leading to the breaking of the chemical bonds, which relies on the absorption of photons. Irradiation with UV photons is preferred … WebJan 27, 2024 · Thus, to simulate the worst-case scenario of HCN volatilization, we assumed 100% photodissociation of total cyanide. Consequently, the six simulated free cyanide concentrations covering the possible range of the total cyanide concentration from 0.26 mg/L (10% of total cyanide) to 2.6 mg/L (100% of total cyanide dissociated by sunlight) …
Photodissociation of cyanide
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WebPhotodissociation of cyclopropyl cyanide at 193 nm has been investigated by measuring laser induced fluorescence spectra of CN fragments that are excl… WebJan 28, 2009 · The U.S. Department of Energy's Office of Scientific and Technical Information
WebThe bond dissociation energy (D0) of the water dimer is determined by using state-to-state vibrational predissociation measurements following excitation of the bound OH stretch fundamental of t WebApr 11, 2024 · Request PDF Signatures of Reaction Mechanisms Encoded in the Vibrational Population Distribution of Small-Molecule Products: Photodissociation of Symmetric-Triazine Using 266 nm Radiation We ...
WebJul 28, 2004 · Photodissociation dynamics of cyclohexyl cyanide and cyclohexyl isocyanide at 193 nm has been investigated by measuring rotationally resolved laser-induced fluorescence spectra of CN fragments in the ground electronic state. From the spectra, rotational and vibrational energy distributions as well as translational energy releases in … WebThe photodissociation of cyanide from ferric myoglobin (MbCN) and horseradish peroxidase (HRPCN) has definitively been observed. This has implications for the interpretation of ultrafast IR (Helbing et al. Biophys. J. 2004, 87, 1881–1891) and optical (Gruia et al. Biophys. J. 2008, 94, 2252–2268) studies that had previously suggested the …
WebPhotodissociation of vinyl cyanide at 193 nm: Nascent product distributions of the molecular elimination channels J Chem Phys. 2009 Jan 28;130 (4):044307. doi: …
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